recent strides in new directions

Are they still electrifying? Electrochemically switchable rotaxanes are well known for their ability to efficiently undergo changes of (co-)conformation and properties under redox-control. Thus, these mechanically interlocked assemblies represent an auspicious liaison between the fields of molecular switches and molecular electronics. Since the first reported example of a redox-switchable molecular shuttle in 1994, improved tools of organic and supramolecular synthesis have enabled sophisticated new architectures, which provide precise control over properties and function. This perspective covers recent advances in the area of electrochemically active rotaxanes including novel molecular switches and machines, metal-containing rotaxanes, non-equilibrium systems and potential applications

Tetrathiafulvalene – a redox-switchable building block to control motion in mechanically interlocked molecules

With the rise of artificial molecular machines, control of motion on the nanoscale has become a major contemporary research challenge. Tetrathiafulvalenes (TTFs) are one of the most versatile and widely used molecular redox switches to generate and control molecular motion. TTF can easily be implemented as functional unit into molecular and supramolecular structures and can be reversibly oxidized to a stable radical cation or dication. For over 20 years, TTFs have been key building blocks for the construction of redox-switchable mechanically interlocked molecules (MIMs) and their electrochemical operation has been thoroughly investigated. In this review, we provide an introduction into the field of TTF-based MIMs and their applications. A brief historical overview and a selection of important examples from the past until now are given. Furthermore, we will highlight our latest research on TTF-based rotaxanes

A mechanism for the non-Fermi-liquid behavior in CeCu_{6-x}Au_x

We propose an explanation for the recently observed non-Fermi-liquid behavior of metallic alloys CeCu_{6-x}Au_x: near x=0.1, the specific heat c is proportional to T \ln (T_0/T) and the resistivity increases linearly with temperature T over a wide range of T. These features follow from a model in which three-dimensional conduction electrons are coupled to two-dimensional critical ferromagnetic fluctuations near the quantum critical point, x_{c}=0.1. This picture is motivated by the neutron scattering data in the ordered phase (x=0.2) and is consistent with the observed phase diagram.Comment: 4 pages, LaTeX, 3 figure

Quark mass thresholds in QCD thermodynamics

We discuss radiative corrections to how quark mass thresholds are crossed, as a function of the temperature, in basic thermodynamic observables such as the pressure, the energy and entropy densities, and the heat capacity of high temperature QCD. The indication from leading order that the charm quark plays a visible role at surprisingly low temperatures, is confirmed. We also sketch a way to obtain phenomenological estimates relevant for generic expansion rate computations at temperatures between the QCD and electroweak scales, pointing out where improvements over the current knowledge are particularly welcome.Comment: 14 pages. v2: minor additions and clarifications; published versio

Chiral corrections to the isovector double scattering term for the pion-deuteron scattering length

The empirical value of the real part of the pion-deuteron scattering length can be well understood in terms of the dominant isovector $\pi N$-double scattering contribution. We calculate in chiral perturbation theory all one-pion loop corrections to this double scattering term which in the case of $\pi N$-scattering close the gap between the current-algebra prediction and the empirical value of the isovector threshold T-matrix $T_{\pi N}^-$. In addition to closing this gap there is in the $\pi d$-system a loop-induced off-shell correction for the exchanged virtual pion. Its coordinate space representation reveals that it is equivalent to $2\pi$-exchange in the deuteron. We evaluate the chirally corrected double scattering term and the off-shell contribution with various realistic deuteron wave functions. We find that the off-shell correction contributes at most -8% and that the isovector double scattering term explains at least 90% of the empirical value of the real part of the $\pi d$-scattering length.Comment: 4 pages, 2 figures, to be published in The Physical Review

The static quark potential to three loops in perturbation theory

The static potential constitutes a fundamental quantity of Quantum Chromodynamics. It has recently been evaluated to three-loop accuracy. In this contribution we provide details on the calculation and present results for the 14 master integrals which contain a massless one-loop insertion.Comment: 6 pages, talk presented at Loops and Legs in Quantum Field Theory 2010, W\"orlitz, Germany, April 25-30, 201

3-D unrestricted TDHF fusion calculations using the full Skyrme interaction

We present a study of fusion cross sections using a new generation Time-Dependent Hartree-Fock (TDHF) code which contains no approximations regarding collision geometry and uses the full Skyrme interaction, including all of the time-odd terms. In addition, the code uses the Basis-Spline collocation method for improved numerical accuracy. A comparative study of fusion cross sections for $^{16}O + ^{16,28}O$ is made with the older TDHF results and experiments. We present results using the modern Skyrme forces and discuss the influence of the new terms present in the interaction.Comment: 7 pages, 10 figure

The Casimir Energy for a Hyperboloid Facing a Plate in the Optical Approximation

We study the Casimir energy of a massless scalar field that obeys Dirichlet boundary conditions on a hyperboloid facing a plate. We use the optical approximation including the first six reflections and compare the results with the predictions of the proximity force approximation and the semi-classical method. We also consider finite size effects by contrasting the infinite with a finite plate. We find sizable and qualitative differences between the new optical method and the more traditional approaches.Comment: v2: 14 pages, 11 eps figures; typo in eq. (21) removed, clarification added, fig. 10 improved; version published in Phys. Rev.